Eco-foam Fun

Developers:

Information from National Science Teacher's Association Conference (1998) that was core of 1998 SCIBUS hands on workshops for teachers.

Grade Levels:

K through 12

Discipline:

Physical Science / Chemistry

Goals:

  1. Students will conduct several activities using Eco-foam (a material containing cornstarch and polyvinyl alcohol).

  2. Students will learn about the chemistry of polymers.

  3. Students will observe various polymer behaviors (e.g. Non-Newtonian / viscoelastic fluid flow).

Background:

Eco-foam

Eco-foam is a packing material composed of mostly cornstarch and a small amount of polyvinyl alcohol. It is ecologically safe and biodegradeable, so it will not add to landfill overflow. Numerous companies, like Carolina Biological®, pack shipments in it, so it should be easily available to teachers. There are kits available that provide materials and instructions for several activities using Eco-foam, but nothing is difficult to get or to make.

Teacher's Notes:

In Activity 1, the Eco-foam material you make fizzles, shrinks and dissolves. The Eco-foam creates bubbles upon dissolution with the release of trapped air in the foam.

In Activity 2, the Eco-foam material you make is a slimy gel that can be used as a glue.

In Activity 3, the Eco-foam material you make is a glob of gel with very interesting viscoelastic properties.

In Activity 4, the Eco-foam material from activity 3 is blown into a balloon.

In Activity 5, there is an investigation of various types of glues and there interaction with the Borax (cross linker) solution.

In Activity 6, a ball very different from the one in Activity 3 is made.

In Activity 7, we do a Silly Putty® type of image transfer operation.

In Activity 8, we see an example of Non-Newtonian fluid behavior.

Materials:

  • Eco-foam packing material
  • water
  • teaspoon
  • white glue (Elmer's®)
  • plastic or paper cups
  • coffee stirrer sticks
  • borax (20-Mule Team®, see laundry section of the supermarket)
  • food coloring (optional)
  • drinking straws
  • sandwich or snack size zipper (zip lock) storage bags
  • colored comics from the Sunday newspaper
  • empty plastic soda bottle
  • different type(s) of glue (other than white, for example mucilage or other gum based)

Explanation:

The Chemistry of Glue

White glue (like Elmer's®) contains a chemical called poly vinyl acetate. You may have heard of vinyl plastics. Shower curtains and "Saran" food wrap are made of vinyl plastics. The word plastic means something can be shaped or molded easily.

Most of the glue is water. The tiny plastic particles are dispersed or suspended in the water. When the white glue dries, the water evaporates into the air, and the solid plastic particles come together and stick to each other and to certain other things that the glue is next to. The poly vinyl acetate particles in white glue are actually coated with another chemical called poly vinyl alcohol that keeps them from sticking to each other in the bottle and helps keeps them suspended in the water.

Plastic Particles Dispersed in Water

Chemists call mixtures, like the white glue, colloids. Mayonnaise is also a colloid. Mayonnaise is made from egg yolks, vegetable oil and water. The egg yolk coats droplets of the oil and keeps the oil suspended or held up in the water so the oil and water do not separate.

The Chemistry of Polymers

Poly is prefix that means many. Polymer means many parts. Pmolecules that are like long chains with many links made of smaller molecules. Molecules are groups of atoms.

Polymers are very important substances. Wood, starch, rubber, cotton, wool, spiders' webs, silk, hair, leather, muscles and fingernails are all examples of polymers that are made in nature. Man-made polymers, or synthetic polymers, are materials such as polyester, polystyrene, polyethylene, teflon®, nylon® and the material in the white glue. Fibers in clothing, carpets and fishing line are all polymers.

All polymers contain many parts and are made from monomers. The prefix mono means one. Monomer means one part. The monomers link up like a zipper to form the polymer. Polymers may contain hundreds and thousands of parts. Chemists use symbols and models to simplify writing the structures. The diagram shows only a few of the hundreds of parts in a polymer. The arrow is used to show the starting materials that are on the life side are changed to the products on the right side. The arrow can be read as "produce", "go to", "change" or "yields".

Monomer molecules yielding part of the polymer molecule diagram

The Chemistry of the Cross-Linker

The cross-linker for our experiment is the solution of borax and water (with a little food coloring). Sodium tetraborate decahydrate is the chemical name for borax. It's chemical formula is Chemical formula of Borax. Na is the symbol for the element sodium; B is the symbol for the boron; and O is for oxygen. Na comes from the word natrium, which is the old Latin name for sodium. The numbers in the formula mean that there are 2 sodium, 4 boron and 7 oxygen atoms combined to make borax. But you have to pour it out of the box to get borax. The 10 Chemical formula of water means that there are 10 water molecules attached to each borax. Deca is a prefix meaning ten and hydrate means water.

The cross-linker is a solution of borax mixed and dissolve in water. Solutions flow just like the water that they are made from, but colloids and gels do not flow like water.

The Molecular Net

When the cross-linker is mixed with the glue and water, chemical bonds break and new bonds form and the bonds link the molecules together. This cross-link forms a network and traps the water in the molecular net. The Goofy Gel is mostly water, but the cross-links make it more rigid and keep the gel from flowing like water.

For more information on the Borax - water chemistry please go to our It's The Slime Time of Your Life experiment.

Cross-links also occur, in a similar way, during hair permanents to make the hair curly. Blood clots occur when protein fibers in the blood stick to each other by cross-linking.

Questions:



References:



Procedure:

Prepare the Borax Cross-Linker Solution

  1. Dissolve 1 teaspoon Borax in 1/2 cup water and stir until dissolved.
  2. Add several drops of food coloring (optional).

ACTIVITY 1: ECO-FOAM FIZZLE

  1. Add 1 teaspoon (5 ml) of water to a cup.
  2. Add 2 or 3 pieces of Eco-foam to the cup.
  3. DO THE FIZZLE by stirring the cup contents with a coffee stirring stick.

What happened?
Why did the Eco-foam fizzle and create bubbles?

ACTIVITY 2: ECO-FOAM GLUE

  1. Use the ECO-FOAM FIZZLE in a cup from Activity 1.
  2. Add 4 - 5 drops of Borax solution to the cup containing the ECO-FOAM FIZZLE.
  3. Stir the cup with a coffee stirring stick.

What did you make (description)?
What happens when, using the stirring stick as an applicator, you put the material between two pieces of paper?

ACTIVITY 3: GOOFY GEL BALL

  1. Add 1 teaspoon (5 ml) of water to a cup.
  2. Add 1 teaspoon (5 mil) of white glue to the water.
  3. Use a coffee stirring stick to
    • scrape all the glue off the spoon; and
    • mix the glue and water together.

  4. Add about 1/5 teaspoon (1 ml) of Borax solution to the glue-water in the cup.
  5. Stir with the coffee stirring stick.

What did you get?
What happens when you roll the material into a ball and try to bounce it?
What happens when you pull the material slowly?
What happens when you pull the material apart quickly? How does it break?
What happens when you put the pieces together?
Store the material in a zipper bag to keep it from drying out.

ACTIVITY 4: GOOFY GEL BALLOON

  1. Use the GOOFY GEL BALL (in the zip lock bag) from Activity 3.
  2. Place your goofy gel ball on one end of a straw.
  3. Blow gently through the other end of the straw.
      If necessary, pinch the gel to seal any leaks, especially around the straw.

What happened?

ACTIVITY 5: ARE ALL GLUES THE SAME? (ACTIVITY 3 WITH OTHER GLUES)

  1. Note what type of glue you are using.
  2. Add 1 teaspoon (5 ml) of water to a cup.
  3. Add 1 teaspoon (5 mil) of the other (not white) glue to the water.
  4. Use a coffee stirring stick to
    • scrape all the glue off the spoon; and
    • mix the glue and water together.

  5. Add about 1/5 teaspoon (1 ml) of Borax solution to the glue-water in the cup.
  6. Stir with the coffee stirring stick.

What did you get?
What happens when you roll the material into a ball and try to bounce it?
What happens when you pull the material slowly?
What happens when you pull the material apart quickly? How does it break?
What happens when you put the pieces together?
Summarize the difference between the product from this glue and what you got with the white glue.

ACTIVITY 6: ECO-FOAM GEL BALL

  1. Use the ECO-FOAM GLUE (in a cup) from Activity 2.
  2. Add several more Eco-foam nuggets to the cup.
  3. Stir the contents using the coffee stirring stick.

Can you form a gel ball?
Do you need to add more Borax cross-linker?
How do the properties of your Eco-foam gel ball differ from those of your Goofy gel ball made with white glue (Activity 3)?

ACTIVITY 7: GOOFY FOAM PICTURES

  1. Use the GOOFY GEL BALL (in zip lock plastic bag) from Activity 3 (or make some more).
  2. Knead it (or pull and roll it) around in your hands until it is not sticky.
  3. Press on a colored picture from the Sunday comics in the newspaper and try to pick up the image.

The ink will be transferred to the goofy gel. (Note that this will not work on papers that have been coated, such as magazines.)

ACTIVITY 8: GOOFY FLOW

  1. Use the GOOFY GEL BALL (in zip lock plastic bag) from Activity 3 (or make some more)
  2. Make a funnel by carefully cutting the top from an empty soda bottle.
  3. Put the goofy gel in the funnel and watch it flow.
  4. Push on the gel and watch how it gets bigger as it is pushed through.

The goofy gel swells or dilates as pressure is applied to it. This is one property of Non-Newtonian fluids.


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